SMARTLINE-PV | Fast plasma-assisted perovskite crystallization for high efficiency lead-free perovskite thin film photovoltaics

Summary
Metal halide perovskite solar cells have moved into the focus of energy materials research through impressive power conversion efficiencies. However, the most efficient perovskite absorbers contain toxic lead. Tin halide perovskites have emerged as a highly promising alternative and efficiencies up to 14.6% have been already reported, but to become a highly efficient thin film technology, further increasing their efficiency and stability, as well as fast and homogeneous large area perovskite crystallization compatible with roll-to-roll processes are still major hurdles. These challenges are tackled within SMARTLINE-PV by the development of a fast, robust and scalable plasma assisted crystallization technology leading to high quality tin perovskite films. The benefits lie in the high speed of the process, the low temperatures involved and in the precise control of perovskite nucleation and growth by a combination of the precursor chemistry and the plasma conditions. Moreover, (i) tailored interlayers will be applied to further improve the solar cell efficiency and stability and (ii) novel device concepts to fabricate flexible tin perovskite solar cell modules with selectable colour will be implemented.
The lead-free thin film PV technology developed in SMARTLINE-PV will achieve efficiencies of 25%, with significant reduction of energy consumption and manufacturing costs compared to other thin film technologies, which typically involve high temperature steps. For the SMARTLINE-PV consortium, these advancements will lead to a plethora of new opportunities to strengthen the European photovoltaics industry in many sectors including the important building-integrated (BI) PV market. Ecodesign, circularity and social acceptance will play important roles in the whole development process in which a TRL progression of tin perovskite solar cells to TRL 5 is foreseen, which will be validated by the fabrication of BIPV-demonstrators and their operation in real-life conditions.
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More information & hyperlinks
Web resources: https://cordis.europa.eu/project/id/101122327
Start date: 01-01-2024
End date: 30-06-2027
Total budget - Public funding: 4 994 686,25 Euro - 4 994 686,00 Euro
Cordis data

Original description

Metal halide perovskite solar cells have moved into the focus of energy materials research through impressive power conversion efficiencies. However, the most efficient perovskite absorbers contain toxic lead. Tin halide perovskites have emerged as a highly promising alternative and efficiencies up to 14.6% have been already reported, but to become a highly efficient thin film technology, further increasing their efficiency and stability, as well as fast and homogeneous large area perovskite crystallization compatible with roll-to-roll processes are still major hurdles. These challenges are tackled within SMARTLINE-PV by the development of a fast, robust and scalable plasma assisted crystallization technology leading to high quality tin perovskite films. The benefits lie in the high speed of the process, the low temperatures involved and in the precise control of perovskite nucleation and growth by a combination of the precursor chemistry and the plasma conditions. Moreover, (i) tailored interlayers will be applied to further improve the solar cell efficiency and stability and (ii) novel device concepts to fabricate flexible tin perovskite solar cell modules with selectable colour will be implemented.
The lead-free thin film PV technology developed in SMARTLINE-PV will achieve efficiencies of 25%, with significant reduction of energy consumption and manufacturing costs compared to other thin film technologies, which typically involve high temperature steps. For the SMARTLINE-PV consortium, these advancements will lead to a plethora of new opportunities to strengthen the European photovoltaics industry in many sectors including the important building-integrated (BI) PV market. Ecodesign, circularity and social acceptance will play important roles in the whole development process in which a TRL progression of tin perovskite solar cells to TRL 5 is foreseen, which will be validated by the fabrication of BIPV-demonstrators and their operation in real-life conditions.

Status

SIGNED

Call topic

HORIZON-CL5-2022-D3-03-05

Update Date

12-03-2024
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Horizon Europe
HORIZON.2 Global Challenges and European Industrial Competitiveness
HORIZON.2.5 Climate, Energy and Mobility
HORIZON.2.5.0 Cross-cutting call topics
HORIZON-CL5-2022-D3-03
HORIZON-CL5-2022-D3-03-05 Novel Thin Film (TF) technologies targeting high efficiencies
HORIZON.2.5.2 Energy Supply
HORIZON-CL5-2022-D3-03
HORIZON-CL5-2022-D3-03-05 Novel Thin Film (TF) technologies targeting high efficiencies