EnSurf | Enantioselectivity at surfaces: covalent grafting as new tool for chiral surface modifications

Summary
Chiral surfaces have received considerable attention in the recent past since they play an important role as substrates for chiral separations and enantioselective heterogeneous catalysis. One of the most frequently used approaches to design and fabricate chiral surfaces is the adsorption and self-assembly of chiral or prochiral molecules on surfaces, which can be studied with sub-molecular resolution by scanning tunneling microscopy (STM). Thereby, the fabrication of homochiral surfaces is of particular interest. However, a major drawback of this approach is, in particular in view of potential applications, the lack of stability of physisorbed molecules. Therefore, EnSurf aims to use covalent surface modifications as chiral surface modifiers and new experimental approach for the creation of homochirality and enantioselectivity in self-assembling molecular structures at the solid/liquid interface.
This interdisciplinary project takes place in the field of surface and interface science and involves aspects of supramolecular chemistry, synthetic chemistry, analytical chemistry and theoretical chemistry. Ultimately, this project will allow the fellow to attain professional independence and a position at the frontier of future academic or industrial research by a combination of hands-on experience in diverse research areas and training in complementary skills.
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More information & hyperlinks
Web resources: https://cordis.europa.eu/project/id/789865
Start date: 01-03-2018
End date: 29-02-2020
Total budget - Public funding: 160 800,00 Euro - 160 800,00 Euro
Cordis data

Original description

Chiral surfaces have received considerable attention in the recent past since they play an important role as substrates for chiral separations and enantioselective heterogeneous catalysis. One of the most frequently used approaches to design and fabricate chiral surfaces is the adsorption and self-assembly of chiral or prochiral molecules on surfaces, which can be studied with sub-molecular resolution by scanning tunneling microscopy (STM). Thereby, the fabrication of homochiral surfaces is of particular interest. However, a major drawback of this approach is, in particular in view of potential applications, the lack of stability of physisorbed molecules. Therefore, EnSurf aims to use covalent surface modifications as chiral surface modifiers and new experimental approach for the creation of homochirality and enantioselectivity in self-assembling molecular structures at the solid/liquid interface.
This interdisciplinary project takes place in the field of surface and interface science and involves aspects of supramolecular chemistry, synthetic chemistry, analytical chemistry and theoretical chemistry. Ultimately, this project will allow the fellow to attain professional independence and a position at the frontier of future academic or industrial research by a combination of hands-on experience in diverse research areas and training in complementary skills.

Status

CLOSED

Call topic

MSCA-IF-2017

Update Date

28-04-2024
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Horizon 2020
H2020-EU.1. EXCELLENT SCIENCE
H2020-EU.1.3. EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions (MSCA)
H2020-EU.1.3.2. Nurturing excellence by means of cross-border and cross-sector mobility
H2020-MSCA-IF-2017
MSCA-IF-2017