Summary
We will develop new dual catalytic reactions based on the complementary reactivity of gold (I) and other transition metals. We will perform well developed gold-catalysed isomerisation reactions and intercept carbenoid intermediates through a transmetallation event with a more redox active metal such as palladium (0). Following this the resulting palladium carbenoid will perform a variety of cross-coupling reactions including: dimerisations, C-X insertions and C-H insertions. This approach has not been reported previously and would provide new reactions and disconnections for the synthetic chemist. This project will be delivered by Dr Tapas Ghosh, a highly experienced and accomplished researcher currently working at Izmir Institute of Technology, Turkey.
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More information & hyperlinks
| Web resources: | https://cordis.europa.eu/project/id/660398 |
| Start date: | 18-07-2016 |
| End date: | 17-07-2018 |
| Total budget - Public funding: | 195 454,80 Euro - 195 454,00 Euro |
Cordis data
Original description
We will develop new dual catalytic reactions based on the complementary reactivity of gold (I) and other transition metals. We will perform well developed gold-catalysed isomerisation reactions and intercept carbenoid intermediates through a transmetallation event with a more redox active metal such as palladium (0). Following this the resulting palladium carbenoid will perform a variety of cross-coupling reactions including: dimerisations, C-X insertions and C-H insertions. This approach has not been reported previously and would provide new reactions and disconnections for the synthetic chemist. This project will be delivered by Dr Tapas Ghosh, a highly experienced and accomplished researcher currently working at Izmir Institute of Technology, Turkey.Status
CLOSEDCall topic
MSCA-IF-2014-EFUpdate Date
28-04-2024
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